H315 Causes skin irritation. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. The central nervous system (CNS) is the primary target organ for toluene toxicity in both humans and animals for acute (short-term) and chronic (long-term . The hazard symbol is a picture of a cylinder or container of compressed gas surrounded by a circle. 2,4-Toluene diisocyanate is extremely toxic from acute (short-term) and chronic (long-term) exposures. Hazard symbol(s) and hazard statement (s) Toluene > 99.0 108-88-3 203-625-9 Flam. Generally, commercial material comes as a mixture of the two isomers. This may include collecting personal and area air samples. 108-88-3 Toluene >99 203-625-9 Hazard Symbols: XN F Risk Phrases: 11 20 Section 3 - Hazards Identification Emergency Overview Appearance: Colorless. 584-84-9 . H304 : May be fatal if swallowed and enters airways. 128. Exposure to toluene may occur from breathing ambient or indoor air affected by such sources. Toluene Standard Fuel 93.4 Version 1.9 Revision Date 2016-05-20 SDS Number:100000013850 1/16 SECTION 1: Identification of the substance/mixture and of the company/undertaking . H304 - May be fatal if swallowed and enters airways. Hazard class table. What is Toluene 3. : 601-021-00-3 CAS-No. Digitally printed for vivid colors on designs or logos. May be fatal if swallowed and enters airways. Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapour. 67/548/EC . Flammable liquid and vapor. 108-88-3 RTECS No. These cement are mostly used to seal joints in concrete, wood, metal, or masonry buildings. Aspiration hazard, Category 1 Labeling Symbol(s) : Signal Word: Danger Hazard Statements : H225: Highly flammable liquid and vapor. Reactivity Alerts none Air & Water Reactions Reproductive and developmental toxicity of toluene: a review. Slightly soluble in water and neutrally buoyant in water. May cause drowsiness or dizziness. Donald, J. M., K. Hooper, et al. Research & Laboratory Chemicals, Gas Chromatography Solvents, Toluene GC grade, GC0800 Health Hazards . Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconscious- ness and coma. : 108-88-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . Hazard Symbols Symbol GHS05 GHS05. Toluene, a flammable liquid with a pungent odor, is widely employed as an organic solvent. Signal: Danger. H315 : Causes skin irritation. Hazard Summary Toluene is added to gasoline, used to produce benzene, and used as a solvent. TOLUENE Maximum concentration 500 ppm N/A OSHA Z2 TOLUENE TWA 200 ppm N/A OSHA Z2 TOLUENE TWA 20 ppm N/A ACGIH NOTE: Limits/standards shown for guidance only. Column 3: Hazard Class or Division . It contains a benzene ring attached to a methyl group. Name: p-Tolunitrile: Synonyms: 4-Methylbenzenecarbonitrile para-tolunitrile p-toluonitrile 4-Methylbenzonitrile P-toluenenitrile . Toluene Synonyms & Trade Names Methyl benzene, Methyl benzol, Phenyl methane, Toluol CAS No. 2,4-Toluene diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. specifies only "TWO" NFPA 704 approved symbols. National Institutes . The chemical formula of toluene can be written as C6H5CH3. TOLUENE RECTIFIED For Synthesis Methylbenzene. toluene 1. identification product name: toluene chemical family: aromatic hydrocarbon cas # 108-88-3 synonyms: toluene, toluol, methylbenzene 2. hazards identification emergency overview flammable liquid and vapor. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. What is Xylene 4. %W/W CAS No. Page 6 of 16 MSDS - Toluene . Toluene | C6H5CH3 or C7H8 | CID 1140 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Toluene mixes readily with many organic solvents, but is poorly soluble in water. may be harmful if swallowed. GHS Classification. Signal word Danger. Toluene diisocyanate. Long-term effect can affect the liver and kidney function. . The substance may cause effects on the central nervous system. Aspiration hazard, Category 1 Acute aquatic toxicity, Category 2 Hazard Symbol : Signal Word : Danger Hazard Statements : H225 : Flammable liquid and vapor. aspiration hazard. Application T 1856 (OTTO) Toluene, 99% Cas 108-88-3 - used as a recreational inhalant and has the potential of causing severe neurological harm. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Supplier and Substance Identification . Special Remarks on Explosion Hazards: Vapors may form explosive mixtures in air. : 1294 IMCO Class No. 6. Vapors may form explosive mixtures with air. H332 : Harmful if inhaled. HIGHLY FLAMMABLE LIQUID AND VAPOUR. H317 May cause an allergic skin reaction. Decomposes with emission of toxic oxides of nitrogen at high temperatures. Alcoholic beverage consumption can enhance the toxic effects of this substance. Durable laminate that increases the label strength and resistance. Liq. Symbol (GHS) Signal word Danger Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. Aromatic odour. Find here p-Toluene sulphonyl chloride, 98% manufacturers, suppliers & exporters in India with worldwide shipping. . 1; H304 Skin Irrit. Lastly, The MSDS identification of Toluene was explained in Table 1 above. Hazard statements H315-H318. Benzene (C 6 H 6) is a clear, colourless and flammable liquid with a sweet petrol-like smell. "Hazard symbols or warning symbols are recognisable symbols designed to warn about hazardous materials, locations, or objects, including electric currents, poisons, and radioactivity. Precautionary statements P280-P305 + P351 + P338. H319 : Causes serious eye irritation. May cause sensitization by skin contact. Cyclohexene appears as a colorless liquid. The 'Substance identity' section is calculated from substance identification information from all ECHA databases. Hazard statements Causes skin irritation. P260 Do not breathe dust/fume/gas/mist/vapours/spray. California No Significant Risk Level: None of the chemicals in this product are listed. Most orders ship within 2 business days. Sign design conforms to OSHA 29 CFR 1910.145 standard for header style, text format and header color. 2 mil thick white polyester with matte finish. By referring from the hazard symbols in laboratory. ), Category 1 H330 Fatal if inhaled . Most important symptoms and effects, both acute and delayed: Irritation.Shortness of breath.Headache.Nausea.Dizziness.The substance is irritating to the eyes and respiratory tract. GHS Toluene Labels (79654) Toluene: Highly flammable liquid and vapor. Hazards Insoluble in water and less dense than water. 2,4-Toluene diisocyanate . Workers may be harmed from exposure to toluene. F005; A hazardous waste from nonspecific sources when a spent solvent. Flash point 20F. 2- Agriculture - toluene is used as a pesticide, helping fend off roundworms and hookworms with ease. Irritates skin and eyes. Side by Side Comparison - Toluene vs Xylene in Tabular Form 5. GHS Hazard Statements. Hazards Identification GHS-US classification Acute toxicity (inhal. Suspects of damaging the unborn child by inhalation. Toluene, ACS Toluene, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm - www.P65Warnings.ca.gov Starting from $78.50 Sale $70.65 Order Now Skip to the end of the images gallery Skip to the beginning of the images gallery Price Chart Toluene - Safety rat oral LD50:7.53g/kg. ACCIDENTAL RELEASE . Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or impaired liver or kidney function may be more susceptible to the effects of this substance. Toluene (CHCH) is a colorless liquid with a sweet, pungent odor. Toluene is a clear, colorless liquid which becomes a vapor when exposed to air at room temperature. Chemical name Toluene-2,4-di-isocyanate (4-methyl-m-phenylene diisocyanate) Hazard Statements H330 Fatal if inhaled. Benzene concentrations in fuel were once as high as . 3- Cement - on its own, toluene serves a major purpose in forming cement for fine polystyrene kits. Toxic by ingestion and inhalation. Please indicate on the 91A which of these compounds are known to be present. Follow applicable regulations. Toluene, 2, 4-Disocyanate: 3: 1: 2 : Toluidine, o-3: 2: 0 : Toluidine, p-3: 2: 0 : Tributylamine: 3: 2: 0 . Flammable liquids are: A liquid having a flash point of = 60.5 C (141 F) Any material in a liquid phase with a flash point = 37.8 C (100 F) that is intentionally heated and offered for transport or transported at or above its flash point in bulk packaging. It is insoluble in water, but miscible with benzene, alcohol, ether and other organic solvents. Hazard Summary . Vapors heavier than air. May be toxic by inhalation, ingestion or skin contact. Inhalation of high concentrations may have a narcotic effect. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. Store in a cool, ventilated warehouse. Toluene was first isolated as aromatic extract from the tropical Colombian tree Myroxylon balsamum. Material options might include pipe markers, roll labels and stencils in addition to aluminum, plastic, magnetic backing and paper or vinyl labels. . Severe eye irritant. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. TOLUENE Hazard Class: 3.2 UN/NA . Vinyl toluene (25013-15-4) is also called Vinyltoluene isomers mixture,inhibited; 3,4-vinyltoluene (mixedisomers); alpha,beta-styrene; ar-ethenylmethylbenzene; ar-methyl-styren; ethenylmethyl-benzen; methylethenylbenzene; allyl benzene.It is colorless liquid with a strong, disagreeable odor. Toluene Signs and Labels Here you'll find safety signs, labels and pipe markers, as well as NFPA diamonds, GHS labels, PPE and other warnings for Toluene. Benzene is common in unleaded fuel, where it is added as a substitute for lead, allowing smoother running. A hazard index approach that assumes additive joint action and uses ATSDR Minimal Risk Levels (MRLs) and guidance values based on neurological impairment is recommended for exposure-based assessments of possible neurotoxic health hazards from the four components. General Description A colorless crystalline solid. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. How do you categorize the type of hazards in laboratory? training concerning chemical hazards and controls. 2 mils thick adhesive sticks to all surfaces (even carpets). INGREDIENTS Components CAS Number Concentration (Weight) Toluenediisocyanate, 2,6 91-08-7 20 + 1 Toluenediisocyanate, 2,4 584-84-9 80 + 1 CHEMICAL FAMILY: Isocyanates 3. (In the example, "toluene" is a PSN.) . Toluene Page 2of 8 165/15 Nirvana at Work Ramintra, Ramintra Road, Anusawari, Bang Khen, Bangkok 10220 Thailand Tel : 66 2 1571555 Fax : 66 2 1571556 Call Center : 66 2 1473555 www.apcbkk.com GHS Hazard Statements : H225 Highly flammable liquid and vapour. Toluene is an organic, water-insoluble, liquid aromatic hydrocarbon consisting of a CH3 group attached to a phenyl group. Exposure to toluene can cause eye and nose irritation, tiredness, confusion, euphoria, dizziness, headache, dilated pupils, tears, anxiety, muscle fatigue, insomnia, nerve damage, inflammation of the skin, and liver and kidney damage. From the study all the properties related to the chemical can be found from result. The IUPAC name for toluene is methylbenzene. Less dense than water (7.2 lb / gal) and insoluble in water. CONFINED SPACE HAZARD. Some substance identifiers may have been claimed . : EPA Hazardous Waste No. . The field may also be left . : 3 Packing Group: II Hazardous Statement: H225-H304-H315-H336-H361d-H373 Precaution Statement: P210-P261-P281-P301 + P310-P331. It was designed on the base of the table from the Wikimedia Commons article "GHS hazard symbols". Hence floats on water. hazard ratings may have colored backgrounds with contrasting colored numerals or colored numerals with a white background. Used in aviation and automotive fuels, as a solvent, and to make other chemicals. Category 2 - Highly flammable liquid and vapor. Study with Quizlet and memorize flashcards containing terms like Explosives (Hazard Class 1) Division 1.1: Mass Explosion Hazard Examples: Black powder, dynamite, T-N-T, Explosives (Hazard Class 1) Division 1.2: Projection Hazard Examples: Aerial Flares, detonation cord, and power device cartridges., Explosives (Hazard Class 1) Division 1.3: Fire Hazard Examples: Liquid-fueled rocket motors . Emergency Response Guide No. Toluene is a common component in gasoline, glues, and paint products. WARNING: This product contains Toluene, a chemical known to the state of California to cause developmental reproductive toxicity. 2,4-TDI is produced in the pure state. literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Toluene is a clear, colorless, volatile liquid with a sweet, pungent, benzene-like odor. Flammability: 3 (Serious) What is Toluene? The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees. Inhalation of vapor may cause respiratory tract irritation. may cause respiratory tract, eye and skin irritation. The special U220; A toxic waste when a discarded commercial chemical product or manufacturing chemical intermediate or an off-specification commercial chemical product or manufacturing chemical intermediate. Machine washable for fabrics. More Info. Protection from direct sunlight. Toluene is an organic compound having the chemical formula C 7 H 8. NFPA Hazard ID: Health: 2 Flammability: 3 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 3 Reactivity: 0 . Find more information on this substance at: PubChem . 77, No. It is flammable at temperatures greater than 40F (4.4C); therefore, it is a significant fire hazard at room temperature. Examples of some D-1 materials include carbon monoxide, sodium cyanide, sulphuric acid, toluene-2,4-diisocyanate (TDI), and acrylonitrile. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: 02/27/2018 Supersedes: 03/21/2014 Version: 1.1 . Toluene is a naturally occurring compound derived primarily from petroleum or petrochemical processes. If you are carrying out classification of substances and/or mixtures (chemical products) you are strongly advised to carefully go through the whole of Part 1 of the Guidance on the application of CLP criteria document. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Company Fisher Scientific Company One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acros Organics One Reagent Lane Fair Lawn, NJ 07410 Skin Corrosion/Irritation . A PSN. | CDC < /a > Cyclohexene appears as a precursor for synthesizing benzene ; H315 STOT 3. 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